Enzymatic Synthesis of α-Anomer-Selective <small>D</small>-Glucosides Using Maltose Phosphorylase

Kuniki KINO; Yu SHIMIZU; Shoko KURATSU; Kohtaro KIRIMURA

doi:10.1271/bbb.70117

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Enzymatic Synthesis of α-Anomer-Selective D-Glucosides Using Maltose Phosphorylase

Kuniki KINO, Yu SHIMIZU, Shoko KURATSU, Kohtaro KIRIMURA

著者情報

キーワード: maltose phosphorylase, α-glucoside, transglycosylation

ジャーナルフリー早期公開

論文ID: 70117

DOI https://doi.org/10.1271/bbb.70117

この記事には本公開記事があります。

The final version of this article is now available: Vol. 71 (2007) , No. 6 p.1598

詳細

抄録

A maltose phosphorylase (EC 2.4.1.8; MPase) showed novel acceptor specificity and transferred the glucosyl moiety of maltose not only to sugars but also to various acceptors having alcoholic OH groups. Salicyl alcohol acted as acceptor for MPase from Enterococcus hirae, and the product, salicyl-O-α-D-glucopyranoside (α-SalGlc) was identified. The yield based on supplied salicyl alcohol was 86% (mol/mol).

責任著者(Corresponding author)

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