抄録
The primary stable products, methyl linoleate monohydroperoxides (MLHPO), formed by the autoxidation of methyl linoleate were characterized by gas chromatography-mass spectrometry. MLHPO was converted into methyl hydroxy stearates which consisted of two isomers, methyl 9-ghydroxy and methyl 13-hydroxy stearate. Trimethylsilyl ether derivatives of these hydroxy isomers were separated directly by gas chromatography and mass fragmentgraphy. MLHPO was degradated by incubating under aerobic condition at 37°C for a week, and the quantity of MLHPO was determined as hydroxy derivatives. Decrease of MLHPO was almost similar to that of conjugated diene structure, but the peroxide value was not appreciably decreased during the incubation. This fact based on the formation of further oxygenated compounds. After chemical reduction, these compounds were identified as methyl 9, 13-hydroxy octadecenoate and methyl 9, 12, 13- or 9, 10, 13-trihydroxy octadecenoate, in which oxygen attached to the conjugated diene. The formation mechanisms of these oxygenated compounds are proposed.
