Agricultural and Biological Chemistry
Online ISSN : 1881-1280
Print ISSN : 0002-1369
ISSN-L : 0002-1369
Metabolism of Isoxathion, O, O-Diethyl O-(5-Phenyl-3-isoxazolyl)-phosphorothionate in Plants
Mitsuru ANDOYukiko IWASAKIMasayuki NAKAGAWA
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1975 年 39 巻 11 号 p. 2137-2143

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The absorption and metabolism of the insecticide, Isoxathion, on bean, cabbage and chinese cabbage plants were examined using carbon-14 labeled compound. Isoxathion penetrated into plant tissues was hydrolyzed to produce 3-hydroxy-5-phenylisoxazole, which was then rapidly converted to water soluble compounds. Among them, 3-(β-D-glucopyranosyloxy)-5-phenylisoxazole, 2-(β-D-glucopyranosyl)-5-phenyl-4-isoxazolin-3-one and 2-(β-D-glucopyranosyl)-5 p-hydroxy-phenyl-4-isoxazolin-3-one were unequivocally identified as the major metabolites. Another metabolic pathway of 3-hydroxy-5-phenylisoxazole via a reductive cleavage of the isoxazole ring to form benzoic acid was negligible.
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© Japan Society for Bioscience, Biotechnology, and Agrochemistry
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