Author's Organization:Organic Synthesis Research Laboratory, Sumitomo Chemical Co., Ltd. Organic Synthesis Research Laboratory, Sumitomo Chemical Co., Ltd. Organic Synthesis Research Laboratory, Sumitomo Chemical Co., Ltd.
Syntheses of a fluorobenzoxazine derivative, fluorobenzothiazine derivative and fluoroquinoxaline derivative are described. These compounds were synthesized by reductive cyclization of the corresponding fluorodinitrobenzene derivatives. The fluorobenzoxazine derivative and its analogues are useful intermediates for agrochemicals.
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