Stereospecific Synthesis of New 4-Amino-1,2,3-cyclohexanetricarboxylic Acids and 4-Amino-1,3-cyclohexanedicarboxylic Acids

Yasushi Arakawa; Manabu Tajima; Yukimi Arakawa; Shigeyuki Yoshifuji

doi:10.1248/cpb.53.81

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Stereospecific Synthesis of New 4-Amino-1,2,3-cyclohexanetricarboxylic Acids and 4-Amino-1,3-cyclohexanedicarboxylic Acids

Yasushi Arakawa, Manabu Tajima, Yukimi Arakawa, Shigeyuki Yoshifuji

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Keywords: 1,2-dihydropyridine, Diels–Alder adduct, ruthenium tetroxide, 4-amino-1,2,3-cyclohexanetricarboxylic acid, 4-amino-1,3-cyclohexanedicarboxylic acid

JOURNAL FREE ACCESS

2005 Volume 53 Issue 1 Pages 81-85

DOI https://doi.org/10.1248/cpb.53.81

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Abstract

Diels–Alder adducts of 1,2-dihydropyridine with maleic and acrylic acid derivatives were stereospecifically converted by way of RuO₄ oxidation into new 4-amino-1,2,3-cyclohexanetricarboxylic acids and 4-amino-1,3-cyclohexanedicarboxylic acids.

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