Oxidative Photo-Decarboxylation in the Presence of Mesoporous Silicas

Akichika Itoh; Tomohiro Kodama; Yukio Masaki; Shinji Inagaki

doi:10.1248/cpb.54.1571

Chemical and Pharmaceutical Bulletin

Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363

J-STAGE home
/
Chemical and Pharmaceutical Bu ...
/
Volume 54 (2006) Issue 11
/
Article overview

Regular Articles

Oxidative Photo-Decarboxylation in the Presence of Mesoporous Silicas

Akichika Itoh, Tomohiro Kodama, Yukio Masaki, Shinji Inagaki

Author information

Keywords: α-amino acid, α-hydroxycarboxylic acid, mesoporous silica, phenylacetic acid derivative, photo-decarboxylation

JOURNAL FREE ACCESS

2006 Volume 54 Issue 11 Pages 1571-1575

DOI https://doi.org/10.1248/cpb.54.1571

Details

Abstract

FSM-16, a mesoporous silica, was found to catalyze oxidative photo-decarboxylation of α-hydroxy carboxylic acid, phenyl acetic acid derivatives and N-acyl-protected α-amino acids to afford the corresponding carbonyl compounds. Furthermore, FSM-16 proved to be re-usable by re-calcination at 450 °C after the reaction.

Content from these authors

Favorites & Alerts

Add to favorites
Additional info alert
Citation alert
Authentication alert

Corresponding author

Register with J-STAGE for free!