A Simple, Iron-Catalyzed, Pyridine-Assisted Hydrogen Peroxide Epoxidation System

Mingyu Jiao; Hirofumi Matsunaga; Tadao Ishizuka

doi:10.1248/cpb.59.799

Communication to the Editor

A Simple, Iron-Catalyzed, Pyridine-Assisted Hydrogen Peroxide Epoxidation System

Mingyu Jiao, Hirofumi Matsunaga, Tadao Ishizuka

著者情報

キーワード: hydrogen peroxide, iron(III) chloride, olefin epoxidation, pyridine, acceleration

ジャーナルフリー

2011 年 59 巻 6 号 p. 799-801

DOI https://doi.org/10.1248/cpb.59.799

詳細

抄録

A simple and inexpensive system comprised of H₂O₂-pyridine-FeCl₃·6H₂O for the catalysis of olefin epoxidation was established. Intriguingly, the reactivity of this system greatly depends on the amounts of pyridine. Various substrates, including aromatic and aliphatic olefins, were epoxidized by this simple system in moderate to excellent yields.

責任著者(Corresponding author)

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