Rhodium-Catalyzed (Perfluoroalkyl)olefination of Acetanilides Leading to Perfluoroalkylated Aromatics

Kohei Harada; Noriyuki Tezuka; Keiichi Hirano; Kazunori Miyamoto; Tatsuo Saito; Masanobu Uchiyama

doi:10.1248/cpb.c16-00588

Communications to the Editor

Rhodium-Catalyzed (Perfluoroalkyl)olefination of Acetanilides Leading to Perfluoroalkylated Aromatics

Kohei Harada, Noriyuki Tezuka, Keiichi Hirano , Kazunori Miyamoto, Tatsuo Saito, Masanobu Uchiyama

Author information

Keywords: perfluoroalkyl (R_F) group, olefination, C–H activation, acetanilide

JOURNAL FREE ACCESS FULL-TEXT HTML
Supplementary material

2016 Volume 64 Issue 10 Pages 1442-1444

DOI https://doi.org/10.1248/cpb.c16-00588

Details

Abstract

We have developed an efficient Rh-catalyzed (perfluoroalkyl)olefination reaction of acetanilides, which provides a versatile synthetic entry to a range of perfluoroalkylated compounds.

Graphical Abstract Fullsize Image

Corresponding author

Register with J-STAGE for free!