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Development of Nitrolactonization Mediated by Iron(III) Nitrate Nonahydrate
2020 年 68 巻 12 号 p. 1220-1225
詳細
2020 年 68 巻 12 号 p. 1220-1225
The nitrolactonization of alkenyl carboxylic acids mediated by Fe(NO3)3·9H2O has been developed. Nitrolactones were obtained in up to 93% yield by treatment of alkenyl carboxylic acids with Fe(NO3)3·9H2O. Mechanistic studies disclosed that the reaction proceeded through a radical intermediate generated from addition of NO2 to alkenyl carboxylic acids.
