Pharmaceutical Bulletin
Online ISSN : 1881-1345
Print ISSN : 0369-9471
ISSN-L : 0369-9471
Benzylamine誘導体の分解(第5報)ベンチルカチオンの芳香性置換反応について その2
砂川 玄俊
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ジャーナル フリー

1955 年 3 巻 2 号 p. 124-131

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抄録
1) The reaction between p-X-C6H4-CH2OH (X=substituent with +M effect) and p-Y-C6H5 (Y=substituent with +M effect) in acid was examined and it was found that products formed in the case of X=CH3O were mainly [chemical formula] and [chemical formula], while in the case of X=(CH3)2N and H2N, [chemical formula] is chiefly formed. 2) p-Methoxybenzyl alcohol undergoes aromatic electrophilic substitution with [chemical formula] and hydrochloric acid. 3) The reaction mechanism whereby diphenylmethane is formed by the aromatic electrophilic substitution of [chemical formula] has been clarified.
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