Pharmaceutical Bulletin
Online ISSN : 1881-1345
Print ISSN : 0369-9471
ISSN-L : 0369-9471
邦産ヤマノイモ科植物のサポニンに就いて(第6報)Gracillinの構造(1)
塚本 赳夫, 川崎 敏男
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ジャーナル フリー

1956 年 4 巻 2 号 p. 104-108

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Gracillin, a new diosgenin glycoside which was present together with dioscin in the water-insoluble saponins obtained from the rhizome of Dioscorea gracillima Miq., was proved to be composed of one mole each of diosgenin and of L-rhamnose and two of D-glucose. It afforded two prosapogenins C and A on partial hydrolysis, both of which were isolated and proved to be trillin (diosgenin monoglucoside) and glucosidoglucoside, respectively. Two possible formulae (I) and (II) were proposed for gracillin.
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© 社団法人 日本薬学会
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