Abstract
In order to find a proto-sapogenin of luvigenin (III), the structural investigation of the unknown sapogenins from Metanarthecium luteo-viride MAXIM was attempted. Isonarthogenin (Va), narthogenin (VIa) and neonogiragenin (XIIIa) were isolated, and the former two sapogenins were established to be steroidal sapogenins having a hydroxyl group at C-27.