Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Reductive Radical Formation of Hetero Aromatic N-Oxides
伊藤 道也岡本 敏彦
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ジャーナル フリー

1967 年 15 巻 4 号 p. 435-439

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抄録
Pyridine 1-oxide gave the 4, 4'-dipyridyl anion radical in 1, 2-dimethoxyethane by reduction with the potassium metal in vacuo. The 3, 5-lutidine, pyrazine and 3-nitropyridine anion radicals were also obtained from the parent N-oxides by the reduction, accompanied with the removal of oxygen atoms, while the 4-nitro- and 4-nitroso-pyridine 1-oxide anion radicals were obtained from the parent compounds without the deoxygenation.
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© The Pharmaceutical Society of Japan
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