Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Biosynthesis of Sinigrin. VI. Incorporation from Homomethionine (2-14C, 15N) and Some Labelled Compounds into Sinigrin
MITSUYOSHI MATSUOMIKIO YAMAZAKI
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1968 Volume 16 Issue 6 Pages 1034-1039

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Abstract
Some labelled compounds were fed to horseradish leaves (Armoracia lapathifolia GILIB.) and yellow mustard seeds (Brassica juncea COSSON). DL-Homomethionine (2-14C, 15N) was directly incorporated into sinigrin in comparison with the other labelled compounds, however DL-allylglycine (2-14C, 15N) was incorporated insignificantly and DL-methionine (2-14C), sodium acetate (2-14C) and sodium malonate (2-14C) were incorporated without randomization. The relationships of their efficient precursors were discussed on sinigrin biosynthesis. Chemical degradation of the allyl thiourea derived labelled mustard oil was described.
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© The Pharmaceutical Society of Japan
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