Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Studies on the Constituents of Leptorumohra Migueliana H. ITO. IV. The NMR Studies of Protofarrerol and Triacetylfarrerol
赤堀 幸男片山 誠二野呂 忠敬福島 清吾斎木 保久上野 明
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1970 年 18 巻 3 号 p. 596-601

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With the analysis of the nuclear magnetic resonance spectra of protofarrerol (IA) and triacetylfarrerol (IIC), the chemical shifts and the coupling constants containing the relative sign are determined using the double resonance techniques, the spin-decoupling and the spin-tickling. Especially the ABX spin systems in these compounds give the similar conformation and the same relative sign of coupling constants, even if the substituent of C-2 position is a phenyl or a alicyclic ring. The computations for the spin systems are carried out with the simulations and the iterations.
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© The Pharmaceutical Society of Japan
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