Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Studies on Cyclic vic-Polyketones. I. Syntheses and Characterization of 1, 2-Disubstituted Cyclopentenetriones
TSUNEYOSHI YAMAZAKITADASHI OOHAMATORU DOIUCHITAKEO TAKIZAWA
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1972 Volume 20 Issue 2 Pages 238-245

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Abstract
Cyclopenten-3, 4, 5-triones having phenyl, methoxy, and dialkylamino groups at their olefinic double bonds were synthesized, and their structural properties were discussed from their infrared and ultraviolet spectra, and pk values. It is proposed that delocali-zability of electron system of the ring is greatly affected by the electron donating ability of the substituent, and that the ring system having strong electron donating groups has a kind of aromaticity.
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© The Pharmaceutical Society of Japan
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