Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Terpenoids. XXVI. Structures of Lasiokaurinol and Lasiokaurinin, Two Novel Diterpenoids of Isodon lasiocarpus (HAYATA) KUDO
EIICHI FUJITAMANABU TAOKATETSURO FUJITA
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1974 Volume 22 Issue 2 Pages 280-285

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Abstract
On the basis of chemical and spectroscopic evidence, the structure and absolute configuration of lasiokaurinol isolated from Isodon lasiocarpus (HAYATA) KUDO were established as ent-1β-acetoxy-7β, 20-epoxy-16-kaurene-6α, 7α, 14α, 15α-tetraol (9). The structure of another minor diterpenoid, lasiokaurinin, was proposed as 10 on the basis of spectroscopic evidence. Some chemical reactions confirmed its structure and relative stereochemistry as 10.
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© The Pharmaceutical Society of Japan
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