Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Studies on the Syntheses of Heterocyclic Compounds. DLXVIII. Catalytic Hydrogenation of (±)-Kreysiginone
亀谷 哲治佐藤 文夫福本 圭一郎杉 秀夫気賀沢 和雄
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1974 年 22 巻 8 号 p. 1835-1838

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Catalytic hydrogenation of the isomeric homoproaporphines (5a and 5b) and the deuterated dienones (6a and 6b) in the presence of platinum catalyst afforded the same mixture of cyclohexanols (7a and 7b). In contrast, reduction of hydrochloride of 5a on palladium-charcoal provided the cyclohexanone (8a) while that of 5b gave a mixture of the cyclohexanone (8b) and the cyclohexenone (9).
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© The Pharmaceutical Society of Japan
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