Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Color Reaction Mechanism of Chinoform by Quinonedichlorodiimide
山本 正康杉村 順子宇野 豊三
著者情報
キーワード: IR spectrum
ジャーナル フリー

1977 年 25 巻 1 号 p. 47-49

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抄録
Quinonedichlorodiimide (I) reacts with chinoform (5-chloro-7-iodo-8-hydroxyquinoline (II)) as well as with 7-iodo-8-hydroxyquinoline-5-sulfonic acid (III) to yield a colored compound. The chemical structure of this compound is investigated from the spectral (infrared, ultraviolet, nuclear magnetic resonance, Mass) data and the elemental analysis. The fact that both the reactions of I+II and I+III give the same compound suggests that I replaces chlorine atom and sulfonic acid group at 5-positions of II and III, respectively. The spectral data supports that the reaction product is 5-qunionediimino-7-iodo-8-hydroxyquinoline.
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© The Pharmaceutical Society of Japan
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