Abstract
Dimethylsulfoxide (DMSO) clathrates of some dithio metal complexes, bis (N-phenyl-β-mercaptothiocinnamamido) metal (II) bidimethylsulfoxide (ML2 (DMSO)2, M : Pt2+, Pd2+, Ni2+), bis {N-(2-methylphenyl)-and bis {N-(2, 6-dimethylphenyl)-β-mercaptothiocinnamamido} palladium (II) bidimethylsulfoxide (PdL'2 (DMSO)2 and PdL2" (DMSO)2, respectively) were prepared. From the results of infrared spectra and magnetic susceptibility measurements, these DMSO molecules were supposed to interact with the thioamido protons of the ligands by forming hydrogen bonds.
