Reactions of 1-Trichloromethyl-substituted Amines with Potassium tert-Butoxide

抄録

The reaction of 1-trichloromethyl-substituted amines with tert-butoxide has been shown to provide important entries into a number of groups of functionalized amines, i. e., 2, 2-dichlorovinylamines (which are also convertible into chloroynamines with a large excess of tert-butoxide), 2, 2-dichloroenamines, N-(α-dichloromethylbenzylidene)-amines and 2, 2-dichloroaziridines. The formation of the products in individual cases depends upon the structure of the amine substrate.