1982 Volume 30 Issue 8 Pages 2820-2824
The title α- and N-halosulfoximides 1-4 undergo base-induced rearrangement reactions to give the same N-sulfinylimines 5, suggesting that these rearrangements all involve the intermediacy of a cyclic sulfoximide, a thiazirine S-oxide 14, which has a novel three-membered ring system with an endocyclic S=N group.