New Methods and Reagents in Organic Synthesis. 43. A New Synthesis of tert-Butyl Peroxycarboxylates Using Diethyl Phosphorocyanidate (DEPC)

YASUMASA HAMADA; AKIRA MIZUNO; TOMOYASU OHNO; TAKAYUKI SHIOIRI

doi:10.1248/cpb.32.3683

YASUMASA HAMADA, AKIRA MIZUNO, TOMOYASU OHNO, TAKAYUKI SHIOIRI

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Keywords: α-effect

JOURNAL FREE ACCESS

1984 Volume 32 Issue 9 Pages 3683-3685

DOI https://doi.org/10.1248/cpb.32.3683

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Abstract

Condensation of carboxylic acids with tert-butyl hydroperoxide has been smoothly achieved by the use of diethyl phosphorocyanidate and triethylamine under mild reaction conditions, giving tert-butyl peroxycarboxylates in good yields.

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