抄録
4-Acetylamino-2-hydroxylaminotoluene (4AA2HAT) and 2-hydroxylamino-6-nitrotoluene (2HA6NT) were prepared from 4-acetylamino-2-nitrotoluene (4AA2NT) and 2, 6-dinitrotoluene (2, 6-DNT), respectively, by reduction with zinc dust and NH4Cl. 2, 6-Dinitrobenzylalcohol (2, 6-DNB) and 2, 6-dinitrobenzoic acid (2, 6-DNBA) were prepared from 2, 6-dinitrobenzaldehyde (2, 6-DNBA1) by reduction with NaBH4 and by oxidation with KMnO4, respectively. 2-Acetylamino-4-aminobenzoic acid (2AA4ABA) was prepared from 4-nitroanthranilic acid (4NAA) by acetylation followed by reduction with NaBH4 and Pd-C. 2, 4-Diacetylaminobenzoic acid (2, 4-DAABA) was prepared from 4NAA by reduction with NaBH4 and Pd-C followed by acetylation. 4-Acetylamino-2-aminobenzoic acid (4AA2ABA) was prepared from 4NAA by reduction and acetylation followed by chelation with Cu(AcO)2.
