Non-enzymatic Oxygenation of (+)-Camphor Catalyzed by Iron(II) Acetonitrile Solvate

Shinobu YAMAKI; Shigeki KOBAYASHI; Eiichi KOTANI; Seisho TOBINAGA

doi:10.1248/cpb.38.1501

Shinobu YAMAKI, Shigeki KOBAYASHI, Eiichi KOTANI, Seisho TOBINAGA

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Keywords: oxygenation, (+)-camphor, iron(II) acetonitrile solvate, hydrogen peroxide, model enzyme, mono-oxygenase, bio-oxygenation

JOURNAL FREE ACCESS

1990 Volume 38 Issue 6 Pages 1501-1503

DOI https://doi.org/10.1248/cpb.38.1501

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Abstract

The oxygenation reaction of (+)-camphor with a simple model reagent, Fe(MeCN)²⁺₆-H₂O₂-Ac₂O, for mono-oxygenase was investigated in connection with its bio-oxygenation. The products 1b, 2b, 3b, 5, 10, 11, and 12 were obtained.

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