THE STERIC EFFECT OF A TRIFLUOROMETHYL GROUP

Takabumi NAGAI; Goro NISHIOKA; Mayumi KOYAMA; Akira ANDO; Takuichi MIKI; Itsumaro KUMADAKI

doi:10.1248/cpb.39.233

永井隆文, 西岡吾朗, 小山まゆみ, 安藤章, 三木卓一, 熊懐稜丸

著者情報

キーワード: trifluoremethyl, ketone, steric effect, ene reaction, dehydration, alcohol, cyclohexene, transition state

ジャーナルフリー

1991 年 39 巻 1 号 p. 233-235

DOI https://doi.org/10.1248/cpb.39.233

詳細

抄録

In the study of ene reaction of trifluoromethyl ketones, a trifluoromethyl group was found to behave as a much larger substituent than commonly believed. Similar results were obtained in the dehydration of trifluoromethyl homoallyl alcohols.

責任著者(Corresponding author)

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