Solvent Effect in the Oxygenation of cis-Stilbene Catalyzed by Non-porphyrin and Porphyrin Iron Complexes

Shigeki KOBAYASHI; Seisho TOBINAGA

doi:10.1248/cpb.39.3025

著者情報

キーワード: oxygenation, cis-stilbene, solvent effect, mixed solvent MeCN-C₆H₆, MeCN-CCl₄, MeCN-CH₂Cl₂, Fe(MeCN)₆·(ClO₄)₂, tetraphenylporphinato iron(III) chloride

ジャーナルフリー

1991 年 39 巻 11 号 p. 3025-3029

DOI https://doi.org/10.1248/cpb.39.3025

詳細

抄録

A solvent effect in the oxygenation reactions of cis-stilbene in the mixed solvents, MeCN-C₆H₆, MeCN-CCl₄, and MeCN-CH₂Cl₂, catalyzed by a non-porphyrin iron(II) complex Fe(MeCN)₆·(ClO₄)₂ and tetraphenylporphinato iron(III) chloride, resulted in significant changes of the product ratio.

責任著者(Corresponding author)

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