Chemical Transformation of Terpenoids. VIII. Anodic Oxidation of Geranyl Acetate

Hirotaka SHIBUYA; Nobutoshi MURAKAMI; Fukiko SHIMADA; Isao KITAGAWA

doi:10.1248/cpb.39.1302

著者情報

キーワード: anodic oxidation, geraniol, geranyl acetate, geranyl acetate 6, 7-epoxide, water-¹⁸O, constant-current electrolysis

ジャーナルフリー

1991 年 39 巻 5 号 p. 1302-1304

DOI https://doi.org/10.1248/cpb.39.1302

詳細

抄録

Constant-current electrolysis of geranyl acetate (2) in CH₃CN-H₂O afforded eight oxidation products (3-10) which were presumed to be formed through initial oxidation of the double bond at C₆-C₇. Based on the results of electrolysis of 2 in CH₃CN-H₂¹⁸O, we have found that the oxygen atom(s) in the products (3-10) is(are) derived from water used as the reaction medium.

責任著者(Corresponding author)

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