EXPLANATION FOR STEREOSELECTIVITY OF THS CIS-DIHYDROXYLATION OF CIS-3, 5-DISUBSTITUTED CYCLOPENTENES

Nobuya KATAGIRI; Yumiko ITO; Kenji KITANO; Akemi TOYOTA; Chikara KANEKO

doi:10.1248/cpb.42.2653

Nobuya KATAGIRI, Yumiko ITO, Kenji KITANO, Akemi TOYOTA, Chikara KANEKO

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Keywords: carbocyclic nucleoside, cis-dihydroxylation, cis-3, 5-disubstituted, cyclopentene, stereoselectivity, steric effect, Cieplak effect

JOURNAL FREE ACCESS

1994 Volume 42 Issue 12 Pages 2653-2655

DOI https://doi.org/10.1248/cpb.42.2653

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Abstract

Stereoselectivity of the cis-dihydroxylation of cis-3, 5-disubstituted cyclopentenes has been found to depend on the conformation of cyclopenetenes and has been explained by both steric and Cieplak effects.

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