Synthesis of (β-N-Sulfonylaminoalkyl)phosphines and Their Use in Palladium-Mediated Asymmetric Synthesis

Shunji SAKURABA; Toshimi OKADA; Toshiaki MORIMOTO; Kazuo ACHIWA

doi:10.1248/cpb.43.927

Shunji SAKURABA, Toshimi OKADA, Toshiaki MORIMOTO, Kazuo ACHIWA

Author information

Keywords: catalytic asymmetric hydrosilylation, catalytic asymmetric Heck-type hydroarylation, palladium complex, aminophosphine

JOURNAL FREE ACCESS

1995 Volume 43 Issue 6 Pages 927-934

DOI https://doi.org/10.1248/cpb.43.927

Details

Abstract

A series of (β-N-sulfonylaminoalkyl)phosphine ligands has been developed and employed for asymmetric palladium-catalyzed hydrosilylation and Heck-type hydroarylation, affording up to 72% ee and 90% yield.

Corresponding author

Register with J-STAGE for free!