Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
SYNTHESIS OF 11Z-8, 18-PROPANO- AND METHANO-RETINALS AND THEIR INTERACTION WITH BOVINE OPSIN
Akimori WADAMasako TSUTSUMIYuka INATOMIHiroo IMAIYoshinori SHICHIDAMasayoshi ITO
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1995 Volume 43 Issue 8 Pages 1419-1421

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Abstract
In order to clarify the conformation of chromophore in rhodopsin, especially the torsional angle around the C6-C7 single bond, 8, 18-propano- and methano-retinals were prepared from 2, 2-dimethylcyclohexanone via the palladium-catalyzed coupling reaction of vinyl triflates with methyl E-3-trimethylstannyl-2-butenoate, and their interaction with bovine opsin was investigated.
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© The Pharmaceutical Society of Japan
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