Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
NOVEL AND FACILE REDUCTION OF HETEROCYCLIC COMPOUNDS WITH LANTHANOID METAL-HYDROCHLORIC ACID SYSTEM
Yasuko KAMOCHI, Tadahiro KUDO
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Keywords: reduction, samarium-hydrochloric acid system, pyridine, quinoline, isoquinoline, piperidine
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1995 Volume 43 Issue 8 Pages 1422-1424

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Abstract
Pyridines were rapidly reduced to piperidines with Sm or Yb-HCl system at room temperature in quantitative yields. Quinolines and isoquinolines were similarly reduced to the corresponding 1, 2, 3, 4-tetrahydro-derivatives with Sm-HCl system in good yields.
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© The Pharmaceutical Society of Japan
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