Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
First Total Synthesis of Mytiloxanthin
Chisato TODE, Yumiko YAMANO, Masayoshi ITO
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Keywords: mytiloxanthin, stereoselective rearrangement, cyclopentyl compound, conjugated enolic β-diketone, total synthesis
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2000 Volume 48 Issue 11 Pages 1833-1834

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Abstract

The first total synthesis of mytiloxanthin 2 was accomplished via the cyclopentyl ketone 7 prepared by stereoselective rearrangement of the epoxide 4a.

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© The Pharmaceutical Society of Japan
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