Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Organic Analysis. XVII. Some Observations on Ultraviolet Spectra of Phenyl Sulfone Derivatives
Tsutomu MomoseYo UedaShujiro Goya
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1959 Volume 7 Issue 8 Pages 862-863

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Abstract
Ultraviolet absorption spectra of phenyl methyl sulfone derivatives were compared with those of benzenesulfonamide derivatives. Introduction of an electron-donating group in the para-position of phenyl methyl sulfone causes a larger bathochromic shift of the first primary band than that in the para-position of benzenesulfonamide, whereas the introduction of electron-attracting group gives hypsochromic shift from the corresponding benzenesulfonamide. Effect of substituents attached to the methyl group of methyl-sulfones on the spectra was also discussed.
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© The Pharmaceutical Society of Japan
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