Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
The Enamine-Immonium Cation System of 9, 10-Dimethoxy-1, 2, 3, 4, 6, 7-hexahydrobenzo [a] quinolizinium Salt
Yoshio BanOsamu Yonemitsu
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1960 Volume 8 Issue 7 Pages 653-655

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Abstract
The enamine, 9, 10-dimethoxy-3, 4, 6, 7-tetrahydro-2H-benzo[a]quinolizine, which was isolated by basifying the aqueous solution of the corresponding immonium chloride, was proved to be reconverted into the immonium cation when dissolved in 85% ethanol to a concentration of ca. 10-4M. The equilibrium between the two is discussed based on its ultraviolet absorption spectra at various pH values.
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© The Pharmaceutical Society of Japan
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