低温生物工学会誌
Online ISSN : 2424-1555
Print ISSN : 1340-7902
低温糖ガラス中における超高速電子位相緩和のフォトンエコーによる測定
長澤 裕小笠原 麻友中川 祐歌子宮坂 博
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2010 年 56 巻 1 号 p. 35-38

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The electronic dephasing times of a chromophore, oxazine 4 (Ox4), doped in low temperature saccharide glasses were investigated by femtosecond photon echo spectroscopy. It was revealed that the dephasing time is much longer in the saccharide glasses compared to hydrogen bonding polymer glass, polyvinylalcohol (PVA), when temperature was lowered to 10 K. A critically damped low frequency oscillation was observed in the signal which can be attributed to the phonon mode of the saccharide glass. The electronic coherence is preserved in the low-temperature saccharide glass due to the restraint thermal fluctuation.
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© 2010 低温生物工学会
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