ノート
Formation of Transition Metal Sulfide Particles by Anode Discharge Electrolysis of Molten LiCl-KCl-KSCN System
2002 年 70 巻 9 号 p. 697-700
詳細
2002 年 70 巻 9 号 p. 697-700
Anode discharge electrolysis has been conducted with a molybdenum anode and a LiCl-KCl-KSCN system under 1 atm of Ar at 723 K. A discharge was generated between the melt and the anode whose tip was positioned above the bath surface. After anode discharge electrolysis, black powder was obtained from the melt. From the results of XRD, SEM, EPMA and XPS, the powder obtained was identified to be MoS2 nano particles. In the same manner, when anode discharge electrolysis was conducted with a tungsten anode, WS2 particles were obtained.
