Electro-reductive Halogen-Deuterium Exchange and Methylation of Aryl Halides in Acetonitrile

Koichi MITSUDO; Takahiro OKADA; Shuichi SHIMOHARA; Hiroki MANDAI; Seiji SUGA

doi:10.5796/electrochemistry.81.362

コミュニケーション

Electro-reductive Halogen-Deuterium Exchange and Methylation of Aryl Halides in Acetonitrile

Koichi MITSUDO, Takahiro OKADA, Shuichi SHIMOHARA, Hiroki MANDAI, Seiji SUGA

著者情報

キーワード: Electro-reduction, Halogen-Deuterium Exchange, Deuteriation, Methylation

ジャーナルフリー

2013 年 81 巻 5 号 p. 362-364

DOI https://doi.org/10.5796/electrochemistry.81.362

詳細

抄録

An electro-reductive halogen-deuterium exchange reaction in CD₃CN has been developed. Using 9-fluorenone as a mediator, the electro-reduction of several aryl halides proceeded smoothly to give the deuterated products selectively. A methylation reaction of aryl halides also proceeded under similar conditions.

責任著者(Corresponding author)

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