低温工学
Online ISSN : 1880-0408
Print ISSN : 0389-2441
ISSN-L : 0389-2441
研究論文
バッファ層に CeO2/Y2O3/CeO2 を用いた Ni めっき Cu/SUS316 貼合せテープ上への YBa2Cu3O7 超電導厚膜の作製
魏 一土井 俊哉勝目 彬人宮永 貴文稲田 満白樂 善則嶋 邦弘窪田 秀一鹿島 直二長屋 重夫
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2012 年 47 巻 5 号 p. 276-281

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In this study, we attempted to install CeO 2 /Y2 O3 /CeO2 buffer layers, where the thicknesses of the CeO2 and Y 2O3 are10 and 250 nm respectively, instead of the CeO 2/YSZ (Y 2O3 stabilized ZrO 2)/CeO2 buffer layer architecture for YBCO (YBa 2 Cu3 O7 ) coated conductors using Ni-electroplated {100}<001> textured Cu and SUS316 laminated tape. Since the diffusion coefficient of oxygen in Y 2O3 is much smaller than that in YSZ and CeO 2, Y 2O3 seems to be a more favorable buffer layer material. We obtained a Jc of 1.0 MA/cm2 for the YBCO/Y 2 O3/Ni-electroplated Cu/SUS 316 laminated tape. However, the Δφvalue of the Y 2O3 layer deposited on the Ni layer increased by 1°compared with that of the Ni layer, and the Δφvalue of the YBCO layer on the Y 2O3 layer increased by 1.5°compared with that of the Y 2O3 layer. To avoid the degradation of the crystal orientations, we inserted very thin CeO2 layers of 10 nm between the Ni and the Y 2O3 layers, and between the Y 2O3 and the YBCO layers. The Jc of the 1 μm-thick YBCO layer prepared on the CeO 2 /Y2 O3 /CeO2 -buffered Ni-electroplated {100}<001> textured Cu/SUS316 laminated tape reached 2.1 MA/cm2 (Ic of 210 A-cm width) at 77 K in a self-field.

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© 2012 公益社団法人 低温工学・超電導学会 (旧 社団法人 低温工学協会)
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