Effect of self and dual-curing on degree of conversion and crosslink density of dual-cure core build-up materials

抄録

Purpose: Dual-cure core build-up resins have been developed to take advantages of both self and light-cured resin. The aim of present study was to determine the polymerization characteristics of self and dual-cured modes of dual-cure core build-up composites evaluating degree of conversion (DC) and crosslink density by measurement of glass-transition temperature (Tg) and hardness decrease in ethanol.

Methods: Clearfil Dc Core Automix (CLF) and Grandio Core Dc (GR) core build-up resins were selected. Twelve specimens for both composites were polymerized using quartz-halogen-tungsten light curing unit (QTH) and 12 specimens polymerized chemically. DC was determined by ATR-FTIR spectroscopy. TG/DTA analysis was performed to determine Tg. Microhardness value of specimens was determined by Vickers-tester before and after specimens stored in absolute ethanol for 24 h.

Results: One-way ANOVA showed no different DC values between dual and self-cured mode of GR and dual-cured CLF composites had higher DC than self-cured mode. Tg and percentage of softening in ethanol values of GR and CLF revealed significant difference between self and dual-cured mode.

Conclusions: In comparison of GR and CLF, DC showed no statistical difference in both curing modes. However, dual and self-cured GR has statistically higher Tg values and lower percentage of softening in ethanol than CLF. Polymerization characteristics of dual-cure core build-up composites have superiority in dual-cured mode than self-cured.