Journal of the Mass Spectrometry Society of Japan
Online ISSN : 1880-4225
Print ISSN : 1340-8097
ISSN-L : 1340-8097
報文
Elimination Processes of Guest Molecules from the Inclusion Complexes of Cholic Acid
Takayoshi KIMURAHideki IMAMURAAkinori SHIMOWADASadao TAKAGI
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ジャーナル フリー

1998 年 46 巻 4 号 p. 304-307

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抄録
Thermal behaviors of the inclusion complexes of cholic acid with propanol, acetylacetone, propylbenzene, and water have been studied by TG-DTA-MS and DSC. Liberation processes of water from their inclusion complexes carried out in a single step. Those of propanol, acetylacetone, propylbenzene from the corresponding inclusion complexes proceeded in only two stages. The elimination temperatures, enthalpies, and the activation enthalpies of eliminations have been determined. Increasing orders of the enthalpies of decomposition and the activation energies of the initial elimination are in agreement with modes of molecular packing reported.
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© 1998 by The Mass Spectrometry Society of Japan
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