Molecular Science
Online ISSN : 1881-8404
Review
DNAモデル塩基対の励起状態二重プロトン移動の協奏的機構と段階的機構の長い論争の始まりから終わりまで
関谷 博迫田 憲治
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ジャーナル オープンアクセス

8 巻 (2014) 1 号 p. A0071-

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Excited-state double-proton transfer (ESDPT) in the coplanar 7-azaindole dimer (7AI2) has been studied as a model base pair. Concerted and stepwise mechanisms were proposed for ESDPT in 7AI2. In the concerted mechanism, two protons transfer concertedly on the excited-state potential energy surfaces where a local minimum does not exist. On the other hand, an intermediate state exists in the stepwise mechanism. Therefore, after one single-proton transfer, the second single-proton transfers via the intermediate state. Numerous spectroscopic and theoretical studies were conducted to determine the mechanism of ESDPT of 7AI2. This review focuses on the ESDPT mechanisms in the gas phase. A prologue and epilogue of the concerted and stepwise mechanism controversy are presented. Spectroscopic experiments in the condensed phase and theoretical calculations related to the potential energy surfaces are important for deriving a final conclusion. In addition, some significant results are comparatively discussed.

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© 2014 分子科学会
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