金属表面技術
Online ISSN : 1884-3395
Print ISSN : 0026-0614
ISSN-L : 0026-0614
ホウ砂とカーボランダムの熱浴による各種金属および各種鋼材の浸ホウ硬化処理の研究
ホウ砂とカーボランダム熱浴による金属表面の浸ホウ処理の研究 (第2報)
吉岡 正三山本 久熊谷 雅晴川本 博茂
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1970 年 21 巻 5 号 p. 276-280

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The bonding of several kinds of pure metals and commercial steels was conducted in a hot salt bath containing 40wt% of carborundum and 60wt% of borax at 1, 000°C.
Boride layers having hardness higher than 2, 000VHN and of less than 15μ in thickness were produced by this process for W, Mo, Ta, and Cr; while for Co, Ni, Zr, and V, the hardness was 1, 200-1, 600VHN and the thickness was more than 100μ.
The boride layers in the former group of metals were composed of higher boride compounds such as WB, CrB, and TaB; while the latter were lower boride compounds such as CO2B, Ni2B, Zr2B, arid V2B.
As for commercial steels, thin boride layers were produced for some steels such as 18-8 stainless steel, 13-Cr stainless steel, and high speed steels; while thick layers were produced for other steels such as steel used for nitriding and high carbon steels. The difference between the both groups of steels would be due to the difference in W, Mo, or Cr content of the steels.

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