1982 年 102 巻 4 号 p. 395-399
The photo-stability and the structures of photo-oxidation products of ethylenediamine and propylenediamine in aqueous solutions with or without theophylline were investigated. Formaldehyde formed from ethylenediamine and propylenediamine, and acetaldehyde from propylenediamine were characterized as 2, 4-dinitrophenylhydrazones. Glyoxal formed from ethylenediamine was characterized as glyoxime. It was found that photodegradation of ethylenediamine and propylenediamine was more rapid in aqueous solutions than in aqueous theophylline solutions.