Azine化合物に関する研究 (第5報)
Benzaldazineの酸化について その1
1952 年 72 巻 11 号 p. 1489-1490
詳細
1952 年 72 巻 11 号 p. 1489-1490
Oxidation of benzaldazine in ether solution with perphthalic acid gives monobenzyl-phthalate, while oxidation with hydrogen peroxide in glacial acetic acid gives benzyl-acetate, Benzaldazine hardly undergoes oxidation in neutral medium The mechanism of the formation of benzylesters by the oxidation of benzaldazine was assumed to be due to the formation of phenyl diazomethane as an intermediate during the reaction.
