YAKUGAKU ZASSHI
Online ISSN : 1347-5231
Print ISSN : 0031-6903
ISSN-L : 0031-6903
Syntheses of Cyanine Dyes. XII
A New Method of Synthesis of Unsymmetrical Trinuclear Dyes containing Two Different Heterocyclic Rings
Yoshihisa TanabeYoshihisa Mizuno
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1953 Volume 73 Issue 3 Pages 237-240

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Abstract
By the reaction of the anilide of thiocarbonyl tetrachloride and quinaldine ethiodide, a new dye, 1, 1′, 1″-triethyl-2, 2′-trimethine-10-anilinoquinolinium iodide was prepared. Application of another mole of quinaldine ethiodide to the latter gave 1, 1′, 1″-triethyl-2, 2′-trimethine-10-quinaldenyl-cyanine iodide, and application of lepidine or 2-methyl-benzothiazole ethiodide gave pinacyanol, with heterocyclic ammonium salt in the 10-position, i.e. a new trimethine dye with three different nuclei.
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