Vitamin B1及び諸関係化合物の研究 第77報
シオール型Thiamine誘導体について その8 Thiamine Alkyl Disulfide類の酸化成績体
1956 年 76 巻 6 号 p. 706-709
詳細
1956 年 76 巻 6 号 p. 706-709
Oxidation of thiamine alkyl disulfides with hydrogen peroxide in acetic acid solution or with perbenzoic acid in chloroform solution results in the formation of a sulfoxide of thiamine alkyl disulfides and this sulfoxide reacts with alkanethiol to form thiamine alkyl disulfides. Oxidation of thiamine benzyl sulfide with hydrogen peroxide in glacial acetic acid gave the sulfoxide of m. p. 133-134° (decomp.).
