Arylsulfuryl Chlorideによるアルコール類の硫酸エステル化(第3報) : モノアルコールの硫酸エステル化ならびにその反応経路について

抄録

Sulfation of various alcohols with phenylsulfuryl chloride (PSC) was carried out and the yields of alkyl hydrogen sulfate produced were compared. Generally, yield of the primary alcohol was found to be more rich than the secondary alcohol, which is better than the tertiary. Nextly, detailed investigations mainly on the reaction products between PSC and ethanol were made and the reaction path presumed were discussed. It was known that a different process path was taken by the different catalysts between pyridine and either NaHCO₃ or Na₂CO₃.