High-grade indium-polymetallic ores of the Toyoha deposits, Hokkaido, which mainly belong to the stage IV mineralization, were studied chemically at E-W trending Shinano-Izumo-Iwami Veins, WNW-ESE trending Soya Vein , and N-S-trending Sorachi-Nemuro Veins. The indium contents go up to 1.0 wt % in the ores (Sorachi, -430 mL). Averaged indium contents and 1000 In/Zn ratio are obtained as follows: Shinano Vein(n=29): 568 ppm and 9.0; Izumo Vein (n=7): 582 ppm and 1.9; Iwami Vein (n=17): 371 ppm and 6.4 (n=16, excluding the highest value of 444.6); Soya Vein (n=4) 1,467 ppm and 3.1; and Nemuro-Sorachi Vein (n=5): 4,050 ppm and 9.1. The whole average is 854 ppm (n=62) and 7.1 (n=61). These indium-rich ores occur in the southeastern part of the Toyoha deposit, where the hydrothermal ore solutions were considered flown out from the depth.
Indium contents of the ores are positively correlated with zinc contents on the Shinano Vein (correlation coefficient of 0.65), but unclear on the whole veins (correlation coefficient of 0.51). Positive correlation between indium and tin is only seen locally (e.g., Iwami Vein). Within available level of 500 meters, zinc content decreases but tin and arsenic contents increase with the depth. Distribution of indium has some similarity with that of tin and arsenic vertically. These chemical characteristics suggest that indium was closely associated with tin and arsenic, besides zinc and cadmium in the hydrothermal fluids. Compared with similar indium-rich ore deposits in sedimentary terrains in Bolivia, indium-contents are similar in the two regions. Mafic components such as iron, copper, nickel, cobalt, arsenic, and silver are, however, richer in the Toyoha deposits than in the Bolivian deposits. Manganese, antimony, bismuth and tin are predominant in the Bolivian ore deposits. These chemical characteristics reflect general difference of the host rocks, juvenile mafic volcanics vs. sedimentary and felsic volcanics, of the two regions.
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