It has been known that the polymeric binder played an important role in the ZnO-resin photo-receptor layer. Despite of the intensive investigations
1)-4), it remained some unclarified aspects associated with the affect of binder in this heterogeneous system such as charge acceptance, carrier generation and, especially, carrier transportation problem.
The present paper reported the results studied about the influence of a variety of organic polymeric binders on the electrophotographic properties of ZnO-resin photo-receptor layer. Within the framework of the charging characteristics, the resins used in this study were classified into four groups (A, B, C, D). It should be noted that the charging with corona of ZnO binded with poly N-vinylcarbazole (group A) was drastically inhibited due to their strong electronic interaction. In order to disperse the microcrystalline ZnO, the weak interaction (dipole-dipole) between ZnO and the resins was necessary at least. Poly styrene and its derivatives (group A) were also ruled out as the binding materials. Conspicuous space charge effects on the photo-discharging were observed in the photo-receptor binded with high insulating resins (group B) at high binder contents. The photo-receptors used the binders of group C (for example, poly γ-Methyl-L-Glutamate), on the other hand, were scarcely affected by the space charge, thus lending support the idea that the binders should play an important role in the carrier-transport process of the photo-receptors.
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